Journal of Pharmaceutical and Biomedical Sciences

Study of Semiconductor Photocatalysed Oxidation of Malic Acid Used in Cosmetic and Food Industries

Pushkar Raj Meena, R. K. Khandelwal

Abstract


Semiconductor photocatalytic process has been widely applied as a ‘green’ technology in treating environmental contaminants, such as the removal of the indoor organic pollutants and the decolourisation and/or degradation of the soluble dyes in waste water. The malic acid is being used in a variety of skin care products, peeling agents including moisturisers, cleansers, eye cream, sunscreen and foundations etc.; where titanium oxide, zinc oxides etc. are used as the base for these materials. Similarly, this acid is also being used as a food and food preservative, curing agent, wine taste enhancer and flavouring agent. As a food additive, titanium dioxide (TiO2) is approved for use in the EU, USA, Australia and New Zealand; it is listed by its INS number 270 or as E number E270. In the present part of work, it is planned to investigate photo-oxidation of malic acid by semiconductors in the very normal conditions. The produced photo-product has been isolated as its derivatives and then analysed them by appropriate spectral or other suitable general methods. Hence, this part of reported work may help to arouse the interdisciplinary interest about the side effects on skin like irritation

Keywords


malic acid, titanium dioxide, semiconductor, photo-oxidation

Full Text:

References


Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode. Nature. 1972;283:37–8.

Frank SN, Bard AJ. Heterogeneous photocatalytic oxidation of cyanide ions in aqueous solution at titanium dioxide powder.J Am Chem Soc. 1977;99:303–4.

Linsebifler AL, Guanquan L, Yates JTJ. Photocatalysis on TiO2 surfaces: principles, mechanisms and selected results. Chem Rev. 1995;95:735–42.

Mao Y, Bakac A. Photocatalytic oxidation of toluene to benzaldehyde by molecular oxygen. J Phys Chem. 1996;100:4219–4226.

El-Morsi TM, Budakowski WR, Abd-El-Aziz AS, Friesen KJ. Photocatalytic degradation of 1,10-dichlorodecane in aqueous suspensions of TiO2: a reaction of adsorbed chlorinated alkane with surface hydroxyl radicals. Environ Sci Technol. 2000;34:1018–1022.

Shah SI, Li W, Huang CP, Jung O, Ni C. Study of Nd3+, Pd2+, Pt4+, and Fe3+ dopant effect on photoreactivity of TiO2 nanoparticles. Proc Natl Acad USA. 2002;99:6482–6486.

Maldotti A, Molinari A, Bergamini A, Amadelli R, Battioni P, Mansuy PDS. Photocatalytic oxidation of cyclohexane by integrated systems. J Mol Catl A-Chem. 1996;113:147–52.

Wang J, Tafen DN, Lewis JP, Hong ZL, Manivannan A, Zhi M, et al. Origin of photocatalytic activity of nitrogen-doped TiO2 nanobelts. J Am Chem Soc. 2009;131:12290–7.

Tan LK, Kumar MK, An WW, Gao H. Transparent, well-aligned TiO2 nanotube arrays with controllable dimensions on glass substrates for photocatalytic applications. ACS Appl Mater Interfaces. 2010;2(2):498–503.

Kamat P. TiO2 nanostructures: recent physical chemistry advances. J Phys Chem Lett. 2012;116:11849–11851.

Veréba G, Manczingerb L, Oszkóc A, Sienkiewiczd A, Forród L, Mogyorósia K, et al. Highly efficient bacteria inactivation and phenol degradation by visible light irradiated iodine doped TiO2. Appl Catal B Environ. 2013;129:194–201.

Listing of specific substances affirmed as GRAS: lactic acid. US FDA. Retrieved 20 May 2013.

UK Food Standards Agency: Current EU approved additives and their E Numbers. Retrieved 27 Oct 2011.

US Food and Drug Administration: Listing of Food Additives Status Part II. Retrieved Oct 2011.

Australia New Zealand Food Standards Code Standard 1.2.4?Labelling of ingredients. Retrieved Oct 2011.

Purac Carcass Applications. Purac. Retrieved 20 May 2013.

Yin ZF, Wu L, Yang HG, Su YH. Recent progress in biomedical applications of titanium dioxide. PCCP. 2013;15(14):458–84.

Sarkar R, Bansal S, Garg VK. Chemical peels for melasma in darkskinned patients. J Cutan Aesthet Surg. 2012;5(4):247–253.

Deprez P. Easy phytic solution: a new alpha hydroxy acid peel with slow release and without neutralization. Int J Cosm Surg Aesth Derm. 2003;5(1):45–51.


Refbacks

  • There are currently no refbacks.


Copyright (c) 2016 Journal of Pharmaceutical and Biomedical Sciences

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.