Computational Biology and Chemistry

Metal Organic Framework and Its Application: A Review

Netra Pal Singh, Anuroop Kumar

Abstract


Metal organic framework compounds (MOFs) are new class compounds. These are also known as porous coordination
polymers. Recent researches increasing day by day because these types of material have more potential. MOF compounds are
constructed from metal ion and organic linkers. This review highlights the MOF compounds formation by different methods and
its potential application in different field like sensor, gas adsorption, and separation; luminescence and biomedical application
are the interesting areas of research in which biomedical field is one of them. The unique physical and chemical characteristics
of MOF makes them promising candidates for drug delivery and drug storage, nitric oxide storage and delivery, imaging and
sensing, adsorption of harmful toxic materials from atmosphere, hydrogen storage and CO2 adsorption catalysis. Porphyrinbased MOF compounds are used in solar photo chemistry. Because of their efficient energy transport properties porphyrinbased MOF are attractive for solar photochemistry application. However, their absorption band provides limited coverage in the visible spectral range for light harvesting application.

MOFs also have wide application in catalysis. The MOF of copper (II) derived from tripodal flexible ligand under hydrothermal
synthesis have catalytic properties in Henry reaction. These framework compounds effectively catalyse the Henry reaction of
nitro ethane with various aldehydes producing the corresponding nitro alkanols in high yield with a significant stereo selectivity
toward the syn diastereomer and also proved the stability and recyclability of catalysts. MOFs also have fluorescent properties;
Mg MOFs work as sensitive fluorescence sensors for CS2 and nitro aromatic compound.


Keywords


MOFs, sensor, luminescence, hydrogen storage, selective gas adsorption

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